Fir chip as the raw materials, H – POs as activator, using single factor analysis and orthogonal experimental design method, this paper discusses the influence granular activated carbon pore structure and the iodine adsorption value, methylene blue and strength of various preparation factors, determine the optimum process conditions of preparation of granular activated carbon phosphoric acid, phosphoric acid concentration is 70%, dipping 180%, kneading temperature is 170 ℃, for 60 min kneading time, activation temperature is 350 ℃, the activation time of 210 min.activated coconut charcoal wholesale
The iodine adsorption value, methylene blue adsorption value, strength and BET specific surface area of GAC were 1020.04mGG, 225mg/g, 88.73% and 1486.48m2/g respectively.The experimental results show that the impregnation ratio and carbon activation temperature have great effects on the adsorption performance of GAC, while the kneading temperature and impregnation ratio have great effects on the strength of GAC.Because the strength of GAC decreases with the increase of impregnation ratio, and the decrease range is large, so the preparation of GAC with compound activator is proposed.pellets carbon
The results show that the composite activator can reduce the impregnation ratio of phosphoric acid to wood chips and improve the strength of granular activated carbon.At the same time, the composite activator can improve the adsorption performance of GAC.Therefore, granular activated carbon with good adsorption performance and high strength can be prepared by this method.Deep desulfurization of transportation fuels is receiving increasing attention in theresearch community worldwide due to increasingly stringent regulations and fuelspecifications in many countries for environmental protection purpose. The traditionalhydrodesulfurization process (HDS) is highly efficient in removing thiols and sulfides, but itis less effective for thiophenes and thiophene derivatives. Ultra-deep desulfurization isbecoming even more formidable challenge for HDS with the decreasing lower sulfur in fuels.Therefore, non-hydrodesulfurization technique of liquid fuels has caused intensive concernsfor ultra-deep desulfurization. Recently, the adsorption desulfurization technique and catalyticoxidation-adsorption desulfurization technique have drawn much attention at home andabroad due to its mild reaction condition,low production cost and little environmentalpollutioz. This thesis focuses on the researches of application of activated carbon fiber inadsorption and oxidation-adsorption removal of thiophenic sulfur compounds from oils.
